Among the numerous methods of processing, conditioning and disinfection of water occupy a significant share of electrochemical methods. This is primarily electrocoagulation, electroflotation, electrolysis, electrochemical oxidation, electrolytic extraction of metals from wastewater and sludge, electropulse water treatment, electrodialysis (Duhin SS, Bolt Lopis VR, Zhovkva EK Electrosurface phenomenon and elektrofiltrovanie - Kiev: Naukova Dumka, 1985. - 286. Ap earnestly NA, Piskarev IM phenol oxidation by an electric discharge. Chemistry and technology of water .- 2001 .- T.23, № 5. - S. 510-514. The electrocatalytic reduction of nitrate in water on Pd / Sn-modified activated carbon fiber electrode. Ying Wang, Jiuhui Qu, Rongcheng Wu el. Water Res .- 2006.-V.40, N6 - P .1224-1232 ) It is known that by using these methods of water treatment on the cathode reaction hydrogen and form deposits, and at the anode, the formation of oxide films and oxygen. In addition to the classical electrochemical methods of water treatment of its expansion can be achieved by photocatalytic processes that use high-performance catalysts developed surface and sunlight. (In situ electrochemical and photochemical generation of the fenton reagent: A potentially important new water treatment technology. Peralta IM, Meas-Vong Y., Rodriguez FI et al / / Water Res .. - 2006. V.40, N9. - P .1754-1762. Casado I., Fornaguera I., Galan MI Pilot scale mineralization of organic acids by electro-Fenton process plus sunlight exposure / / Water res - 2006. V.40, N13 - P.2511 -2516. Iun Wang , Gua Zhang, Zhaohong Zhang et al. / / Investigation on photocatalytic degradation of ethyl violet dyestuff using visible light in the presence of ordinary TiO2 catalystdoped with upconversion luminescene agent / / Water Res .- 2006 .- V. 40, N11 - P. 2143-2150) The source of hydrogen can be processes associated with biochemical sludge and waste of various processes in the first place, such as waste from sugar production, pulp and paper mills and wood waste. (Hydrogen and methane production from household solid waste in the two-stage fermentation process. Liu Dowei, Liu Dapeng, Zeng RI et al. / / Water Res .- 2006 .- V.40, N11 - P.2230-2236. Biological hydrogen production by Clostridium acetobutylicum in an unsaturated flow reactor. Zhang H., Bruns MA, Logan BE / / Water Res .- 2006 .- V.40, N4 - P.728-734. Hydrogen and electricity proguction from a food processing wastewater using fermentation and microbial fuel all technologies. SangEun Oh, BELogan / / Water Res .- 2005 .- V.39, N19 - P.4673-4682) Even an incomplete list of processing water and sediment indicates the presence of a large selection of processes and methods, which can be simultaneously solve two environmental problems. But so far the development of methods for water treatment has been aimed only at getting the final product of pure water. Therefore, the intensification of the use of innovative approaches to creating multi-functional system generation, accumulation of hydrogen - water air conditioning with the requirements of consumers in domestic, international practice and the literature are too often absent.